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Product description
Clear, colorless to yellowish liquid with a pungent odor, which fumes on contact with air and has a boron trifluoride content of at least 51 wt.%.

Chemical name

Adduct of boron trifluoride (BF3)

 
and methanol (2CH3OH)

Trade name

Boron trifluoride Methanol

Ingredient

Boron fluoride-methanol,

 
Boron trifluoride-methanol

Chemical formula

BF3X 2CH3OH

Molecular weight

131.89 g/mol

CAS No.

Boron trifluoride: 7637-07-2

 
Methanol: 67-56-1

EINECS No.

Boron trifluoride: 231-569-5

 
Methanol: 200-659-6

Form supplied and packaging
Supplied in 200 liter sheet steel drums with HDPE inner lining and in 60 liter metal drums with HDPE inner lining. Supply in small containers, tanks or in tank trucks is also possible.

Properties
When stored for relatively long periods it may turn dark in color without losing its application-related properties. On dilution with water, hydrolysis ensues with liberation of methanol. A corrosive, highly acidic mixture of boric acid, hydroxyfluoroboric acids and tetrafluoroboric acid is produced. The vapors released into the air are corrosive. Due to its catalytic properties Boron trifluoride-Methanol adduct reacts with numerous organic compounds.

Melting point

- 20 oC

Flash point

68 oC

Lower explosive limit

approx. 4 vol.%

Ignition point

420 oC

Vapor pressure (20 oC)

4 mbar

Vapor pressure (50 oC)

26 mbar

Density (20 oC)

1.210 - 1.235 g/cm3

Viscosity (20 oC)

2.55 mPa.s

Product specification
See specification Boron trifluoride-Methanol

Certificate
See DIN EN 9001:2000 certificate

Storage and transport
The product must be stored cool and dry in tightly sealed container or tank. Storage tanks must be drained at regular intervals, washed out and inspected. Tanks that have been washed out must be refilled only when they are completely dry. When stored or transported in pressure-resistant tanks the product can be kept under an atmosphere of dry nitrogen.

Applications
For selective reaction control in numerous organic reactions, primarily as a catalyst or cocatalyst.
It can be easily dosed with gear pumps or membrane pumps.

Examples of its uses in the chemical, petrochemical and pharmaceutical industries include:
dimerization
trimerization
oligomerization
polymerization
rearrangement
alkylation
acylation
carbonylation
ring closure
reforming of paraffins
upgrading of lubricants and many others.

Safety
Toxic. Corrosive.
During the handling of these products the data and reference in the safety data sheet are to be considered. In addition the necessary caution and good industrial hygiene while handling chemicals have to been kept.

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